Synthesis of N-Pyridin-2-ylmethyl and N-Quinolin-2-ylmethyl Substituted Ethane-1,2-diamines
نویسندگان
چکیده
منابع مشابه
N-(2-aminobenzyl)-N,N-bis(quinolin-2-ylmethyl)amine.
The title new diquinaldine derivative, C27H24N4, forms molecular assemblies organized by intermolecular quinoline pi-pi stacking [3.356 (3) and 3.440 (3) A] and both inter- and intramolecular N-H...N hydrogen bonds [3.039 (3)-3.104 (3) A and 129 (2)-172 (2) degrees]. The combination of such interactions provides readily definable contacts that propagate along each crystallographic axis.
متن کامل(Acetonitrile){2-[bis(pyridin-2-ylmethyl-κ2 N)amino-κN]-N-(2,6-dimethylphenyl)acetamide-κO}(perchlorato-κO)zinc (acetonitrile){2-[bis(pyridin-2-ylmethyl-κ2 N)amino-κN]-N-(2,6-dimethylphenyl)acetamide-κO}zinc tris(perchlorate)
In the title salt, [Zn(C(22)H(24)N(4)O)(CH(3)CN)][Zn(ClO(4))(C(22)H(24)N(4)O)(CH(3)CN)](ClO(4))(3), two differently coordinated zinc cations occur. In the first complex, the metal ion is coordinated by the N,N',N'',O-tetra-dentate acetamide ligand and an acetonitrile N atom, generating an approximate trigonal-bipyramidal coordination geometry, with the O atom in an equatorial site and the aceto...
متن کاملActivity of a novel sulfonamide compound 2-nitro-N-(pyridin-2-ylmethyl)benzenesulfonamide against Leishmania donovani
New treatments for visceral leishmaniasis, caused by Leishmania donovani, are needed to overcome sustained toxicity, cost, and drug resistance. The aim of this study was to evaluate the therapeutic effects of 2-nitro-N-(pyridin-2-ylmethyl)benzenesulfonamide (2NB) against promastigote and amastigote forms of L. donovani and examine its effect in combination with amphotericin B (AmB) against AmB-...
متن کاملCopper(I) and copper(II) complexes with pyrazine-containing pyridylalkylamide ligands N-(pyridin-2-ylmethyl)pyrazine-2-carboxamide and N-(2-(pyridin-2-yl)ethyl)pyrazine-2-carboxamide
Four copper(II) complexes and one copper(I) complex with pyridine-containing pyridylalkylamide ligands N-(pyridin-2-ylmethyl)pyrazine-2-carboxamide (HL) and N-(2-(pyridin-2-yl)ethyl)pyrazine2-carboxamide (HL) were synthesized and characterized. The X-ray crystal structures of [Cu2(L )2(4,4ʹ-bipy)(OTf )2] (1, OTf = trifluoromethanesulfonate, 4,4ʹ-bipy = 4,4ʹ-bipyridine) and [Cu(L)(py)2]OTf·H2O (...
متن کامل1,2-Bis[(pyridin-2-ylmethyl)sulfanyl]ethane and its dimorphic hydrochloride salt.
Although having been described as a liquid in the literature for 41 years, 1,2-bis[(pyridin-2-ylmethyl)sulfanyl]ethane, C(14)H(16)N(2)S(2), (I), has now been obtained as monoclinic crystals via a new and convenient method of purification. Molecules of (I) are located on crystallographic inversion centres and are held together by C-H···N and C-H···S interactions, resulting in the formation of a ...
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ژورنال
عنوان ژورنال: SynOpen
سال: 2017
ISSN: 2509-9396
DOI: 10.1055/s-0036-1590963